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Industrial Routes from Sugars and Biomass to CMF and Other 5-(Halomethyl)furfurals. ChemSusChem. 2024 Oct 21; 17(20):e202400495.
Bueno Morón J, Arbore F, van Klink GPM, Mascal M, Gruter GM. PMID: 38899763.
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PubMed Mentions: Fields:
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Pseudocannabinoid H4CBD improves glucose response during advanced metabolic syndrome in OLETF rats independent of increase in insulin signaling proteins. Am J Physiol Regul Integr Comp Physiol. 2024 02 01; 326(2):R100-R109.
Wilson JN, Mendez DA, Dhoro F, Shevchenko N, Mascal M, Lund K, Fitzgerald R, DiPatrizio NV, Ortiz RM. PMID: 37899754; PMCID: PMC11283894.
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PubMed Mentions: Fields:
Translation:
HumansAnimals
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Electrochemical Incorporation of Electrophiles into the Biomass-Derived Platform Molecule 5-(Chloromethyl)furfural. ChemSusChem. 2023 Mar 08; 16(5):e202201787.
Ling H, Miao H, Cao Z, Mascal M. PMID: 36525531.
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PubMed Mentions: Fields:
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Cannabidiol Does Not Impair Anabolic Signaling Following Eccentric Contractions in Rats. Int J Sport Nutr Exerc Metab. 2021 03 01; 31(2):93-100.
Langer HT, Mossakowski AA, Pathak S, Mascal M, Baar K. PMID: 33621949.
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PubMed Mentions:
7 Fields:
Translation:
AnimalsCells
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Anion Exchange Doping: Tuning Equilibrium to Increase Doping Efficiency in Semiconducting Polymers. J Phys Chem Lett. 2021 Feb 04; 12(4):1284-1289.
Murrey TL, Riley MA, Gonel G, Antonio DD, Filardi L, Shevchenko N, Mascal M, Moulé AJ. PMID: 33497232.
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PubMed Mentions:
1 Fields:
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Diversification of the Renewable Furanic Platform via 5-(Chloromethyl)furfural-Based Carbon Nucleophiles. ChemSusChem. 2021 Jan 07; 14(1):303-305.
Miao H, Shevchenko N, Otsuki AL, Mascal M. PMID: 32941679.
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PubMed Mentions: Fields:
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Effects of Methyl Branching on the Properties and Performance of Furandioate-Adipate Copolyesters of Bio-Based Secondary Diols. ACS Sustain Chem Eng. 2020 Sep 28; 8(38):14471-14483.
Little A, Pellis A, Comerford JW, Naranjo-Valles E, Hafezi N, Mascal M, Farmer TJ. PMID: 33014637; PMCID: PMC7525809.
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PubMed Mentions:
5
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In Silico Design of Cylindrophanes: The Role of Functional Groups in a Fluoride Selective Host. Chemphyschem. 2020 09 02; 21(17):1989-2005.
Østrøm I, Ortolan AO, Caramori GF, Mascal M, Muñoz-Castro A, Parreira RLT. PMID: 32573902.
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PubMed Mentions: Fields:
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Across the Board: Mark Mascal on the Challenges of Lignin Biorefining. ChemSusChem. 2020 Jan 09; 13(1):274-277.
Mascal M. PMID: 31793729.
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PubMed Mentions:
2 Fields:
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Butenolide Derivatives of Biobased Furans: Sustainable Synthetic Dyes. Angew Chem Int Ed Engl. 2019 11 25; 58(48):17293-17296.
Saska J, Li Z, Otsuki AL, Wei J, Fettinger JC, Mascal M. PMID: 31557374.
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PubMed Mentions:
2 Fields:
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Synthetic, non-intoxicating 8,9-dihydrocannabidiol for the mitigation of seizures. Sci Rep. 2019 05 23; 9(1):7778.
Mascal M, Hafezi N, Wang D, Hu Y, Serra G, Dallas ML, Spencer JPE. PMID: 31123271; PMCID: PMC6533278.
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PubMed Mentions:
11 Fields:
Translation:
Animals
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High-mobility, trap-free charge transport in conjugated polymer diodes. Nat Commun. 2019 05 09; 10(1):2122.
Nikolka M, Broch K, Armitage J, Hanifi D, Nowack PJ, Venkateshvaran D, Sadhanala A, Saska J, Mascal M, Jung SH, Lee JK, McCulloch I, Salleo A, Sirringhaus H. PMID: 31073179; PMCID: PMC6509340.
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PubMed Mentions:
14 Fields:
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A Zwitterionic, 10 π Aromatic Hemisphere. Angew Chem Int Ed Engl. 2017 11 06; 56(45):14141-14144.
Hafezi N, Shewa WT, Fettinger JC, Mascal M. PMID: 28944560.
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PubMed Mentions: Fields:
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New bio-based monomers: tuneable polyester properties using branched diols from biomass. Faraday Discuss. 2017 09 21; 202:61-77.
Arnaud SP, Wu L, Wong Chang MA, Comerford JW, Farmer TJ, Schmid M, Chang F, Li Z, Mascal M. PMID: 28671209.
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PubMed Mentions:
11 Fields:
Translation:
Cells
-
Bio-based materials: general discussion. Faraday Discuss. 2017 09 21; 202:121-139.
Huber G, Argyropoulos D, Matharu A, Bitter H, Stevens C, Herou S, Wilson K, Clark J, Pant D, Cabrera-Rodríguez CI, Samec J, Dale BE, Farmer T, Mascal M, Horan A, Stankiewicz A, Gschwend F, Mu X, Zhou L, Huang X, Hu C, Cooper T, Sparlinek L, Budarin V, Kontturi E, Hunt A, Garrido A, Waldron K, Zhang F, Zhenova A, Constable D, Sarkanen S, Titirici M, Rothenberg G, Albert J, Macquarrie D. PMID: 28879363.
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PubMed Mentions:
1 Fields:
Translation:
Animals
-
Conversion technologies: general discussion. Faraday Discuss. 2017 09 21; 202:371-389.
Argyropoulos D, Bitter H, Brandt-Talbot A, Budarin V, Chesi C, Clark J, Coma M, Crestini C, Dale B, Graca I, Hallett J, Hu C, Huang X, Huber G, Hughes T, Hunt A, Kontturi E, Luo Y, Mascal M, Matharu A, Matveeva V, Mount A, Ouyang X, Rinaldi R, Rothenberg G, Samec J, Sarkanen S, Seidel CM, Stevens C, Thaore V, Waldron K, Wilson K, Xie F, Zijlstra DS. PMID: 28879358.
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PubMed Mentions: Fields:
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Feedstocks and analysis: general discussion. Faraday Discuss. 2017 09 21; 202:497-519.
Aldous L, Argyropoulos D, Budarin V, Cabrera-Rodríguez CI, Clark J, Coma M, Constable D, Fan J, Gschwend F, Hayes D, Hu C, Huber G, Hughes T, Hunt A, Lapkin A, Lye G, Mascal M, Matharu A, Mu X, Pant D, Papaioannou E, Rinaldi R, Rothenberg G, Samec J, Sarkanen S, Stankiewicz A, Stevens C, Titirici M, Waldron K, Wilson K, Zhenova A, Zhou L, Zuin V. PMID: 28879356.
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PubMed Mentions: Fields:
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Bio-based chemicals: general discussion. Faraday Discuss. 2017 09 21; 202:227-245.
Bitter H, Clark J, Rothenberg G, Matharu A, Crestini C, Argyropoulos D, Cabrera-Rodríguez CI, Dale BE, Stevens C, Marrocchi A, Graca I, Luo H, Pant D, Wilson K, Zijlstra DS, Gschwend F, Mu X, Zhou L, Hu C, Lapkin A, Mascal M, Budarin V, Hunt A, Waldron K, Zhang F, Zhenova A, Samec J, Huber G, Coma M, Huang X, Bomtempo JV. PMID: 28879354.
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PubMed Mentions: Fields:
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Electrochemical Coupling of Biomass-Derived Acids: New C8 Platforms for Renewable Polymers and Fuels. ChemSusChem. 2017 Jan 10; 10(1):166-170.
Wu L, Mascal M, Farmer TJ, Arnaud SP, Wong Chang MA. PMID: 27873475; PMCID: PMC5324636.
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PubMed Mentions:
7 Fields:
Translation:
Cells
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Crystal structure determination as part of an undergraduate laboratory experiment: 1',3',3'-tri-methyl-spiro-[chromene-2,2'-indoline] and 1',3',3'-trimethyl-4-[(E)-(1,3,3-tri-methyl-indolin-2-yl-idene)meth-yl]spiro-[chroman-2,2'-indoline]. Acta Crystallogr E Crystallogr Commun. 2016 Nov 01; 72(Pt 11):1659-1662.
Beckett JO, Olmstead MM, Fettinger JC, Gray DA, Manabe S, Mascal M. PMID: 27840731; PMCID: PMC5095856.
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PubMed Mentions:
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Processed Lignin as a Byproduct of the Generation of 5-(Chloromethyl)furfural from Biomass: A Promising New Mesoporous Material. ChemSusChem. 2015 Dec 21; 8(24):4172-9.
Budarin VL, Clark JH, Henschen J, Farmer TJ, Macquarrie DJ, Mascal M, Nagaraja GK, Petchey TH. PMID: 26601798.
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PubMed Mentions:
1 Fields:
Translation:
Cells
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5-(Chloromethyl)furfural is the New HMF: Functionally Equivalent But More Practical in Terms of its Production From Biomass. ChemSusChem. 2015 Oct 26; 8(20):3391-5.
Mascal M. PMID: 26373463.
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PubMed Mentions:
10 Fields:
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Efficient, chemical-catalytic approach to the production of 3-hydroxypropanoic acid by oxidation of biomass-derived levulinic acid with hydrogen peroxide. ChemSusChem. 2015 Apr 13; 8(7):1167-9.
Wu L, Dutta S, Mascal M. PMID: 25736835.
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PubMed Mentions:
4 Fields:
Translation:
Cells
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Novel pathways to 2,5-dimethylfuran via biomass-derived 5-(chloromethyl)furfural. ChemSusChem. 2014 Nov; 7(11):3028-30.
Dutta S, Mascal M. PMID: 25196591.
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PubMed Mentions:
3 Fields:
Translation:
Cells
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Hydrodeoxygenation of the angelica lactone dimer, a cellulose-based feedstock: simple, high-yield synthesis of branched C7 -C10 gasoline-like hydrocarbons. Angew Chem Int Ed Engl. 2014 Feb 10; 53(7):1854-7.
Mascal M, Dutta S, Gandarias I. PMID: 24474249.
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PubMed Mentions:
7 Fields:
Translation:
Cells
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Comment on Gao, W., et al. "Efficient one-pot synthesis of 5-chloromethyl-furfural (CMF) from carbohydrates in mild biphasic systems", Molecules 2013, 18, 7675-7685. Molecules. 2014 Jan 22; 19(1):1367-9.
Mascal M. PMID: 24451255; PMCID: PMC6271857.
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PubMed Mentions: Fields:
Translation:
Cells
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Synthesis of the insecticide prothrin and its analogues from biomass-derived 5-(chloromethyl)furfural. J Agric Food Chem. 2014 Jan 15; 62(2):476-80.
Chang F, Dutta S, Becnel JJ, Estep AS, Mascal M. PMID: 24354505.
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PubMed Mentions:
7 Fields:
Translation:
Animals
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Chemical-catalytic approaches to the production of furfurals and levulinates from biomass. Top Curr Chem. 2014; 353:41-83.
Mascal M, Dutta S. PMID: 24842621.
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PubMed Mentions:
1 Fields:
Translation:
Cells
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Top chemical opportunities from carbohydrate biomass: a chemist's view of the Biorefinery. Top Curr Chem. 2014; 353:1-40.
Dusselier M, Mascal M, Sels BF. PMID: 24842622.
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PubMed Mentions:
19 Fields:
Translation:
Cells
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Synthesis of N-substituted pyrido[4,3-d]pyrimidines for the large-scale production of self-assembled rosettes and nanotubes. J Org Chem. 2013 Nov 15; 78(22):11421-6.
Durmus A, Gunbas G, Farmer SC, Olmstead MM, Mascal M, Legese B, Cho JY, Beingessner RL, Yamazaki T, Fenniri H. PMID: 24131036.
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PubMed Mentions:
2 Fields:
Translation:
Cells
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Extraordinary modes of bonding enabled by the triquinane framework. J Org Chem. 2013 Oct 04; 78(19):9579-83.
Gunbas G, Mascal M. PMID: 24011016.
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PubMed Mentions: Fields:
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Extreme oxatriquinanes: structural characterization of α-oxyoxonium species with extraordinarily long carbon-oxygen bonds. J Am Chem Soc. 2013 Jun 05; 135(22):8173-6.
Gunbas G, Sheppard WL, Fettinger JC, Olmstead MM, Mascal M. PMID: 23682676.
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PubMed Mentions:
1 Fields:
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Extreme oxatriquinanes and a record C-O bond length. Nat Chem. 2012 Dec; 4(12):1018-23.
Gunbas G, Hafezi N, Sheppard WL, Olmstead MM, Stoyanova IV, Tham FS, Meyer MP, Mascal M. PMID: 23174982.
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PubMed Mentions:
5 Fields:
Translation:
Cells
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The R3O+···H+ hydrogen bond: toward a tetracoordinate oxadionium(2+) ion. J Am Chem Soc. 2012 Jan 11; 134(1):707-14.
Stoyanov ES, Gunbas G, Hafezi N, Mascal M, Stoyanova IV, Tham FS, Reed CA. PMID: 22133059; PMCID: PMC3257418.
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PubMed Mentions:
6 Fields:
Translation:
Cells
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Putting anion-π interactions into perspective. Angew Chem Int Ed Engl. 2011 Oct 04; 50(41):9564-83.
Frontera A, Gamez P, Mascal M, Mooibroek TJ, Reedijk J. PMID: 21928463.
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PubMed Mentions:
57 Fields:
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Concise photochemical synthesis of the antimalarial indole alkaloid decursivine. Angew Chem Int Ed Engl. 2011 May 02; 50(19):4445-6.
Mascal M, Modes KV, Durmus A. PMID: 21480441.
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PubMed Mentions:
4 Fields:
Translation:
Cells
-
Azatriquinane as a platform for tripodal metal complexes and calixiform scaffolds. Angew Chem Int Ed Engl. 2011 Jan 17; 50(3):717-9.
Jevric M, Zheng T, Meher NK, Fettinger JC, Mascal M. PMID: 21226161.
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PubMed Mentions:
2 Fields:
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Comment on processes for the direct conversion of cellulose or cellulosic biomass into levulinate esters. ChemSusChem. 2010 Dec 17; 3(12):1349-51.
Mascal M, Nikitin EB. PMID: 21089092.
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PubMed Mentions:
6 Fields:
Translation:
Cells
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1,4,7-Trimethyloxatriquinane: S(N)2 reaction at tertiary carbon. J Am Chem Soc. 2010 Aug 11; 132(31):10662-4.
Mascal M, Hafezi N, Toney MD. PMID: 20681692.
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PubMed Mentions:
12 Fields:
Translation:
Cells
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Dramatic advancements in the saccharide to 5-(chloromethyl)furfural conversion reaction. ChemSusChem. 2009; 2(9):859-61.
Mascal M, Nikitin EB. PMID: 19725092.
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PubMed Mentions:
15 Fields:
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Towards the efficient, total glycan utilization of biomass. ChemSusChem. 2009; 2(5):423-6.
Mascal M, Nikitin EB. PMID: 19408263.
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PubMed Mentions:
5 Fields:
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Oxatriquinane and oxatriquinacene: extraordinary oxonium ions. J Am Chem Soc. 2008 Oct 15; 130(41):13532-3.
Mascal M, Hafezi N, Meher NK, Fettinger JC. PMID: 18798616.
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PubMed Mentions:
7 Fields:
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Aromatic nitration in liquid Ag0.51K0.42Na0.07NO3. J Org Chem. 2008 Aug 15; 73(16):6148-51.
Mascal M, Yin L, Edwards R, Jarosh M. PMID: 18616318.
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PubMed Mentions:
1 Fields:
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Direct, high-yield conversion of cellulose into biofuel. Angew Chem Int Ed Engl. 2008; 47(41):7924-6.
Mascal M, Nikitin EB. PMID: 18671312.
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PubMed Mentions:
34 Fields:
Translation:
Cells
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Aromaticity and curvature in heteroacepentalenes. J Org Chem. 2007 Jun 08; 72(12):4323-7.
Mascal M. PMID: 17503845.
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PubMed Mentions:
1 Fields:
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Fluoride-selective host based on anion-pi interactions, ion pairing, and hydrogen bonding: synthesis and fluoride-ion sandwich complex. Angew Chem Int Ed Engl. 2007; 46(46):8782-4.
Mascal M, Yakovlev I, Nikitin EB, Fettinger JC. PMID: 17935091.
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PubMed Mentions:
11 Fields:
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Synthesis of the G-C DNA base hybrid with a functional tail. J Org Chem. 2006 Oct 13; 71(21):8146-50.
Mascal M, Farmer SC, Arnall-Culliford JR. PMID: 17025304.
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PubMed Mentions:
2 Fields:
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Precedent and theory unite in the hypothesis of a highly selective fluoride receptor. Angew Chem Int Ed Engl. 2006 Apr 28; 45(18):2890-3.
Mascal M. PMID: 16550622.
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PubMed Mentions:
2 Fields:
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Water oligomers in crystal hydrates--what's news and what isn't? Angew Chem Int Ed Engl. 2005 Dec 16; 45(1):32-6.
Mascal M, Infantes L, Chisholm J. PMID: 16307459.
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PubMed Mentions:
9 Fields:
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Interaction of fullerenes with the concave surfaces of perchloroazatriquinacene. Org Lett. 2005 Jul 07; 7(14):2805-8.
Pham D, Cerón Bertran J, Olmstead MM, Mascal M, Balch AL. PMID: 15987141.
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PubMed Mentions: Fields:
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The azaacepentalenide anion: a new aromatic, bowl-shaped heterocycle. J Am Chem Soc. 2005 Feb 09; 127(5):1352-3.
Mascal M, Bertran JC. PMID: 15686349.
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PubMed Mentions: Fields:
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Automatic chiral selection in a thermodynamically predisposed metathesis reaction. Org Lett. 2003 Jul 10; 5(14):2517-8.
Mascal M, Wood IG, Walsgrove T. PMID: 12841769.
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PubMed Mentions: Fields:
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The energetics of shooting ions into the dodecahedrane cage. J Org Chem. 2002 Nov 29; 67(24):8644-7.
Mascal M. PMID: 12444651.
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PubMed Mentions: Fields:
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Anion-aromatic bonding: a case for anion recognition by pi-acidic rings. J Am Chem Soc. 2002 Jun 05; 124(22):6274-6.
Mascal M, Armstrong A, Bartberger MD. PMID: 12033854.
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PubMed Mentions:
30 Fields:
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The Azatriquinenamine Trimer-A Novel Proton Chelate Azatriquinanes, Part 3. This work was financially supported by the University of Nottingham and the Polish State Committee for Scientific Research (grant DS/8231-4-0097-1). We also thank the EPSRC National Crystallography Service, University of Southampton, for data collection. Part 2: Ref [4]. Angew Chem Int Ed Engl. 2001 Oct 01; 40(19):3696-3698.
Mascal M, Lera M, Blake AJ, Czaja M, Kozak A, Makowski M, Chmurzynski L. PMID: 11592226.
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PubMed Mentions: Fields:
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S-Cylindrophanes: From Metal Tweezers to Metal Sandwiches. Angew Chem Int Ed Engl. 1999 Jul 12; 38(13-14):1968-1971.
Mascal M, Kerdelhué JL, Blake AJ, Cooke PA. PMID: 34182676.
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PubMed Mentions:
1 Fields:
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Azatriquinanes: Synthesis, Structure, and Reactivity. J Org Chem. 1998 Aug 21; 63(17):6016-6020.
Hext NM, Hansen J, Blake AJ, Hibbs DE, Hursthouse MB, Shishkin OV, Mascal M. PMID: 11672206.
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PubMed Mentions:
5 Fields: